The transform FROM the coordinate space of the box TO the model space.
Namespace: Autodesk.Revit.DB
Assembly: RevitAPI (in RevitAPI.dll) Version: 2015.0.0.0 (2015.0.0.0)
Syntax
Remarks
The transform must always be right-handed and orthonormal.
Examples

private void RotateBoundingBox(View3D view3d)
{
BoundingBoxXYZ box = view3d.GetSectionBox();
if (false == box.Enabled)
{
TaskDialog.Show("Revit","The section box for View3D isn't enabled.");
return;
}
// Create a rotation transform,
XYZ origin = new XYZ(0, 0, 0);
XYZ axis = new XYZ(0, 0, 1);
// Rotate 2 radians
Transform rotate = Transform.CreateRotationAtPoint(axis, 2, origin);
// Transform the View3D's GetSectionBox() with the rotation transform
box.Transform = box.Transform.Multiply(rotate);
view3d.SetSectionBox(box);
}

Private Sub RotateBoundingBox(view3d As View3D)
Dim box As BoundingBoxXYZ = view3d.GetSectionBox()
If False = box.Enabled Then
TaskDialog.Show("Revit", "The section box for View3D isn't enabled.")
Return
End If
' Create a rotation transform,
Dim origin As New XYZ(0, 0, 0)
Dim axis As New XYZ(0, 0, 1)
' Rotate 2 radians
Dim rotate As Transform = Transform.CreateRotationAtPoint(axis, 2, origin)
' Transform the View3D's GetSectionBox() with the rotation transform
box.Transform = box.Transform.Multiply(rotate)
view3d.SetSectionBox(box)
End Sub